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Max Drickey's avatar

Great post on the necessity of an “all of the above” approach to decarbonization. I find it very telling that in an academic context (where I currently spend most of my time) this is really a matter of settled science.

I’m absolutely guilty of having wanted to pick the technologies that fit my meet my political preferences (and deride those that fit the preferences of my political opponents) but truly we are not in a position to leave some of our tools in the shed. There is indeed a clear role for energy with high levelized costs and for energy with low levelized costs, for CCUS and DAC and nuclear, etc.

I think it’s also refreshing that regardless of the political debate, the triple threat of BIL, IRA, and the Manchin permitting reform bill clearly demonstrate that policymakers know this also.

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Richard Gadsden's avatar

Just to give people some hard numbers, energy generated per mole of carbon dioxide emitted for the full combustion of some fuels in oxygen: methane: 802.31kJ, n-octane: 634.32kJ, carbon: 393.52kJ.

Natural gas is mostly methane; gasoline averages out as roughly n-octane; coal is very close to being pure carbon.

This gets you a decent estimate at a 4:3:2 ratio of energy per emission for gas : oil : coal. In fact, gas and oil are marginally better than that (gas is about 3.9% better; the composition of oils varies too much to get a number at this level of precision), but both have more emissions in production and refining (gas leaks and emissions in refining), so that tends to balance out.

If you know a bit of chemistry, the explanation is that the enthalpy of formation for water (less the enthalpy of formation for the two carbon-hydrogen bonds you have to break) is almost exactly half the enthalpy of formation of carbon dioxide (-393kJ/mol for carbon dioxide, -241kJ/mol for water vapor and about -37kJ/mol for two carbon-hydrogen bonds, ie half the enthalpy of formation of methane) - which means that four hydrogens in a hydrocarbon will generate about the same energy as one carbon, so the key thing is the carbon:hydrogen ratio in the fuel, which is 1C:4H in methane, 1C:2H in long-chain hydrocarbons and 1C:0H in carbon, ie coal.

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